CaBa-铝酸盐玻璃中Cr4+谱线宽度随温度的变化

测量了15~300K温度范围内57.5%Al_1.5O-35%CaO-7.5%BaO玻璃中四价铬的发射光谱.这种材料中铬离子的能级处于Tanabe-Sugano图上弱场范围中,最低的激发态是³T₂,发射谱是一个宽带.按照单频近似理论拟合低温下的光谱,得到³T₂能级的零声子线位置E_zp=8400cm^-1,声子能量tω=320cm^-1,黄昆因子S=358.尽管单频近似能够较好地描述低温下的线形,发射光谱宽度随温度的变化却与单频近似理论的结果不符.讨论了这种差别的原因,认为可能的解释是与激发态耦合的声子能量大于与基态耦合的声子能量.     

Links between microscopic and macroscopic fluid mechanics

The microscopic and macroscopic versions of fluid mechanics differ qualitatively. Microscopic particles obey time-reversible ordinary differential equations. The resulting particle trajectories {q(t)} may be time-averaged or ensemble-averaged so as to generate field quantities corresponding to macroscopic variables. On the other hand, the macroscopic continuum fields described by fluid mechanics follow irreversible partial differential equations. Smooth particle methods bridge the gap separating these two views of fluids by solving the macroscopic field equations with particle dynamics that resemble molecular dynamics. Recently, nonlinear dynamics have provided some useful tools for understanding the relationship between the microscopic and macroscopic points of view. Chaos and fractals play key roles in this new understanding. Non-equilibrium phase-space averages look very different from their equilibrium counterparts. Away from equilibrium the smooth phase-space distributions are replaced by fractional-dimensional singular distributions that exhibit time irreversibility.     

Spectrofluorimetric Determination of Trace Amounts of Gallium with Salicylaldehyde Benzoylhydrazone

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Gaussian Property of the Rings R(X) and R〈X〉

The content of a polynomial f over a commutative ring R is the ideal c(f) of R generated by the coefficients of f. A commutative ring R is said to be Gaussian if c(fg) = c(f)c(g) for every polynomials f and g in R[X]. A number of authors have formulated necessary and sufficient conditions for R(X) (respectively, R?X?) to be semihereditary, have weak global dimension at most one, be arithmetical, or be Prüfer. An open question raised by Glaz is to formulate necessary and sufficient conditions that R(X) (respectively, R?X?) have the Gaussian property. We give a necessary and sufficient condition for the rings R(X) and R?X? in terms of the ring R in case the square of the nilradical of R is zero.     

无胺合成[Fe]ZSM-5分子筛的结构鉴定及其催化性能的研究

不用有机胺为模板剂,在碱性介质中采用水热合成法成功地合成了[Fe]ZSM-5分子筛.用X射线衍射、透射电镜、红外光谱、顺磁共振谱、X射线光电子能谱和穆斯堡尔谱等对其结构进行了表征,结果表明,Fe原子进入了分子筛骨架,并处于四面体的配位环境.在由甲醇转化为汽油的过程中,以本文合成的[Fe]ZSM-5与用有机胺为模板剂合成的[Fe]ZSM-5分子筛为催化剂相比,其活性和选择性几乎相同,且都比通常的H[Al]ZSM-5好,C₅组分以上的选择性大于80%,且芳烃(包括脂环烃)和异构烃的含量达75%以上.     

On a Penalty-Perturbation Theory for Plate Problems

A penalty-perturbation method previously proposed by Westbrook(J. Inst. Maths Applics (1974) 14, 79–82) for the solutionsof static bending problems for elastic plates is analysed here.The method replaces the single fourth-order biharmonic equationby a system of three second-order equations which is "singularly"perturbed with respect to a small penalty parameter . The existenceof solutions of the perturbed problem for each > 0 is establishedand the behaviour of these solutions as 0 0 is studied. Inparticular, the results show that while these solutions arecontinuous in at = 0, analyticity in at = 0 is lost exceptin special cases.     

磷对冷轧纯铜再结晶的影响

本文研究了微量磷对冷轧纯铜再结晶的影响。当磷原子主要是溶解在铜中时,大大提高了再结晶温度,增加了再结晶激活能,阻止了立方结构的形成,改变了再结晶结构;但出氧化磷状态存在于铜中时,对以上各方面的影响就不很明显。所有样品的再结晶结构,都与加工结构中的某一种取向相同或接近,并且与主要加工结构间存在着沿<111>相差20—45°的几何关系。分析从金相及X光研究后得到的结果,认为在这种情况下,同位再结晶和选择性生长是再结晶结构形成的过程。 关键词：     

Solubilization chromatography: Ethers,carboxylic acids,and hydrocarbons

Synthetic mixtures of aliphatic and aromatic ethers, satmated fatty acids, and substituted benzenes and naphthalenes were separated by elution through columns of ion-exchange resins with aqueous solutions of acetic acid as eluent An attempt was made to use a resin of low capacity for the separation of such mixtures, and the results of this attempt are used to help elucidate the theory of solubilization chromatography     

DSC Study on Brain Tubulin and the Effect of Cisplatin

Microtubules, a class of cytoskeletal elements, appear to be present in all eukaryoticcells. The temporal and spatial control of assembly and disassembly of microtubulesis believed to be a key factor in cellular function. Microtubules and their subunits(Q-0 tubulin heterodimers, MW 1 10,000) maintain a dynamic equilibrium in the cellcytoplasm. In addition, it is postulated that the lability of cytoplasmic microtubulescaused by drug is related to their equilibrium. Calorimetry method has been…